Inventors:
Willie Lau - Lower Gwynedd PA, US
Donald C. Schall - Lansdale PA, US
Kimberly B. Kosto - Maple Glen PA, US
Joseph M. Rokowski - Barto PA, US
Assignee:
Rohm and Haas Company - Philadelphia PA
International Classification:
C08J 11/04
US Classification:
521 41, 521 40, 521 405, 521 425, 521 435, 521 44, 528480, 528499, 528520 R, 528502 F, 528503, 516 9, 516 98, 524 68, 524 71, 524922, 525 50, 525 55, 525 56, 525232, 428141, 428147
Abstract:
The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 μm or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 μm in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.