Inventors:
Ronald D. Bushick - Glen Mills PA
Howard P. Angstadt - Media PA
Assignee:
Sun Ventures, Inc. - Philadelphia PA
International Classification:
C07C12014
Abstract:
An ammoxidation process for preparing nitriles from m- and p-xylene whereby the formation of carbon oxides is held to a minimum which comprises reacting the xylene and ammonia at a temperature of from about 375. degree. C. to about 500. degree. C. and in the presence of added oxygen, the molar ratio of ammonia to xylene being about 3:1 or less, the molar ratio of oxygen to xylene being about 3:1 or less, the volume percent concentration of the feed being preferably about 3% to 10% hydrocarbon, 7% to 20% ammonia, and 10% to 20% oxygen, and the catalyst for said reaction comprising at least about 1 to 10% by weight of a vanadium bronze supported on. alpha. -alumina.