Inventors:
Anthony F. Kasenga - Towanda PA
A. Gary Sigai - Lexington MA
Thomas E. Peters - Chelmsford MA
Roger B. Hunt - Medfield MA
Assignee:
GTE Products Corporation - Danvers MA
GTE Laboratories Incorporated - Waltham MA
International Classification:
C09K 1159
Abstract:
A method for producing manganese activated zinc silicate phosphor wherein the individual phosphor particles are surrounded with a non-particulate, conformal aluminum oxide coating is disclosed. The method comprises dry blending a mixture of components consisting essentially of zinc oxide, silicic acid, a source of manganese, ammonium chloride, ammonium fluoride, tungstic oxide, and silica, wherein the Zn+Mn/Si mole ratio is from about 1. 95 to about 2. 02, wherein the silica is colloidal and has a surface area of from about 50 to about 410 m. sup. 2 per gram, and wherein the colloidal silica makes up from about 0. 01% to about 1. 0% by weight of the mixture; firing the resulting dry blend of components in a nitrogen atmosphere at a temperature of from about 1200. degree. C. to about 1300. degree. C. for a sufficient time to produce the phosphor; milling the resulting phosphor for a period of time of from about 60 minutes to about 120 minutes; firing the resulting milled phosphor in air at a temperature of from about 1175. degree. C.