Inventors:
Robert C. Ryan - Houston TX
Assignee:
Shell Oil Company - Houston TX
International Classification:
C10G 4500, C10G 4710, B01J 2104, B01J 2112
Abstract:
The instant invention relates to a method for preparing a hydrotreating catalyst having improved hydrodenitrification activity by impregnating an alumina supported Group VIB/Group VIII hydrogenating catalyst with a liquid form of a silicon compound having the general formula ##STR1## wherein U, V, W, X, Y, and Z can individually be --R, --OR, --Cl, --Br, --SiH. sub. 3, --COOR, --SiH. sub. n Cl. sub. m, R being either hydrogen, or an alkyl, cycloalkyl, aromatic, alkyl aromatic, alkylcycloalkyl radical having from 1 to 30 carbon atoms, "n" and "m" being whole numbers in the range of from 1 to 3 and "a" being a whole number in the range of from 0 to 80, in an amount sufficient to deposit from about 2 to about 8 percent by weight of the total catalyst of Si, and subsequently calcining said impregnated catalyst at a temperature ranging from about 300. degree. C. to about 600. degree. C. in an oxidizing atmosphere.