Inventors:
Keith A. Klinedinst - Hudson MA
Robert F. Clark - Brockton MA
Assignee:
Osram Sylvania Inc. - Danvers MA
International Classification:
H01J 162
US Classification:
313503, 313483, 313502, 427212, 427213, 427 70, 428404, 428403, 428698, 428704
Abstract:
A phosphor particle has thereon a moisture resistant treatment of a metallic nitride. By moisture resistant is meant a condition allowing the phosphor particle to function in a humid atmosphere for a significantly longer period of time than an untreated particle. The method of making such phosphors comprises the steps of introducing an inert gas into a reaction vessel; charging phosphor particles into the reaction vessel; heating the reaction vessel to a reaction temperature; introducing a nitride coating precursor into the reaction vessel; introducing a co-reactant into the reaction vessel; and maintaining the inert gas flow, co-reactant flow and precursor supply for a time sufficient to moisture-proof the phosphor particles. The nitride treated phosphor particles produced by this method, which can include the deposition of a nitride coating on the particles, have excellent efficacy ratings and strong luminance values in lamps after 100 hours use in high humidity (i. e. , 95%).