Inventors:
Sara I. Kopponen - Anchorage AK, US
Ralph T. Goodwin - Ponca City OK, US
Kristi A. Fjare - Ponca City OK, US
Barbara A. Belt - Seabrook TX, US
Brian J. Levitt - Aurora CO, US
Richard J. Wissbaum - Littleton CO, US
Mariella L. Raven - Houston TX, US
Frank B. Walter - Englewood CO, US
Assignee:
ConocoPhillips Company - Houston TX
International Classification:
C07C 27/00, B01J 20/34
US Classification:
518710, 518709, 518715, 502 22, 502 38, 502 44
Abstract:
Embodiments of the invention relate to processes and apparatus for the washing and recovery of metal-containing catalyst solids in a form suitable for reclamation. More specifically, a catalyst recovery process comprises removing an organic residue with a washing medium from a metal-containing catalyst solids, recovering washed solids, and treating the washed solids under oxidative conditions to form non-reactive solids. The treatment oxidative conditions may be effective to convert the metal(s) into an oxide form and/or may facilitate the removal of remaining organic residue from the washed solids. The treatment of the washed solids may comprise calcination. In some embodiments, the metal-containing catalyst solids may be recovered from a slurry stream, and the process further comprises passing the slurry stream though a separation unit to obtain a catalyst-enriched retentate slurry. In some embodiments, the organic residue comprises a hydrocarbon wax, and the solid catalyst is a hydrocarbon synthesis particulate catalyst.