Inventors:
Nety M. Krishna - Sunnyvale CA, US
Ralf Hofmann - Soquel CA, US
Kaushal K. Singh - Santa Clara CA, US
Karl J. Armstrong - San Jose CA, US
International Classification:
H01L 21/28, H01L 29/788
US Classification:
257316, 438594, 257E21158, 257E293
Abstract:
In one embodiment, a method for forming a metallic nanocrystalline material on a substrate is provided which includes exposing a substrate to a pretreatment process, forming a tunnel dielectric layer on the substrate, exposing the substrate to a post-treatment process, forming a metallic nanocrystalline layer on the tunnel dielectric layer, and forming a dielectric capping layer on the metallic nanocrystalline layer. The method further provides forming the metallic nanocrystalline layer having a nanocrystalline density of at least about 5×10cm, preferably, at least about 8×10cm. In one example, the metallic nanocrystalline layer contains platinum, ruthenium, or nickel. In another embodiment, a method for forming a multi-layered metallic nanocrystalline material on a substrate is provided which includes forming a plurality of bi-layers, wherein each bi-layer contains an intermediate dielectric layer deposited on a metallic nanocrystalline layer. Some of the examples include 10, 50, 100, 200, or more bi-layers.