Inventors:
Patricia A. Morris - Wilmington DE
Assignee:
E. I. Du Pont de Nemours and Company - Wilmington DE
International Classification:
C01B 2526, C01G 2802, C30B 3100
Abstract:
A process is disclosed for treating a crystal of MTiOXO. sub. 4 which has crystal structure deficiencies of M and O, wherein M is selected from the group consisting of K, Rb, Tl and NH. sub. 4 and mixtures thereof and X is selected from the group consisting of P, As and mixtures thereof, which includes the step of heating said crystal in the presence of a mixture of MTiOXO. sub. 4 and at least one inorganic compound of one or more monovalent cations selected from the group consisting of Rb+, K+, Cs+ and Ti+ (said inorganic compound(s) being selected to provide a source of vapor phase monovalent cation and being present in an amount sufficient to provide at least a 0. 1 mole % excess of the monovalent cation in relation to the M in the MTiOXO. sub. 4 in said mixture) at a temperature of from about 400. degree. C. to 950. degree. C. and a pressure of at least 14 psi, and in the presence of a gaseous source of oxygen for a time sufficient to decrease the optical damage susceptibility of said crystal.