Inventors:
Robert A. Meyer - St. Louis MO
William A. Smith - Houston TX
Mark A. Mueller - Austin TX
Gregory B. Demoll - LaGrange Park IL
Assignee:
Texaco Chemical Company - White Plains NY
International Classification:
B01D 340, C07D30132
Abstract:
Impure propylene oxide is purified by a distillation process wherein it is (a) extractively distilled in a first column using a C. sub. 2 to C. sub. 6 alkylene glycol extractive distillation agent to form a first overhead fraction comprising propylene oxide, C. sub. 5 -C. sub. 7 hydrocarbons methanol, water and oxygen-containing impurities, (b) wherein the first overhead fraction is separated in a second column into a second overhead fraction comprising most of the pentanes, pentenes and oxygen-containing impurities and a partially purified propylene oxide bottoms fraction comprising propylene oxide, hexenes, hexanes, and only residual quantities of pentenes and pentanes, (c) wherein the partially purified bottoms fraction is extracting distilled in a third column using a C. sub. 7 -C. sub. 10 alkane hydrocarbon extractive distillation agent to provide a further purified bottoms fraction containing substantially all of the propylene oxide, hexenes, hexanes charged to the third distillation column, and (d) the further purified bottoms fraction is extractively distilled in a fourth column using a C. sub. 7 to C. sub. 10 alkane hydrocarbon extractive distillation agent to provide a purified propylene oxide overhead fraction consisting essentially of propylene oxide.