John C. McIntyre
Engineering at Countryside Dr, Hackettstown, NJ

5399751, Mar 21, 1995

Nov 5, 1993

8/147394

Joseph C. Gentry - Dallas TX
John C. McIntyre - Hackettstown NJ
Timothy L. Holmes - Kingwood TX
Ronald G. Gualy - Dallas TX

Glitsch, Inc. - Dallas TX

C07C 5142

562608

Disclosed is a method for recovering carboxylic acids having from one to ten carbon atoms, and particularly formic acid, acetic acid and mixtures of formic and acetic acids, from aqueous solutions, in which the aqueous solution is contacted with solvent consisting essentially of mixed trialkylphosphine oxides in counter-current liquid-liquid extraction flow in a contacting step to thereby transfer the acids from the aqueous solution to the solvent, thus producing a raffinate relatively low in acid content and a rich solvent. The rich solvent is preferably dehydrated to separate water therefrom and yield a dehydrated rich solvent. The dehydrated rich solvent then has the acids stripped from it and the resulting lean solvent is then returned to the liquid-liquid extraction step, while the separated acids are split into their constituent components in a distillation operation.

5399244, Mar 21, 1995

Dec 6, 1993

8/163025

Joseph C. Gentry - Dallas TX
Lloyd Berg - Bozeman MT
John C. McIntyre - Hackettstown NJ
Randa W. Wytcherley - Belgrade MT

Glitsch, Inc. - Dallas TX

B01D 340, C07C 708

203 23

Benzene and other aromatics are separated from a stream of mixed hydrocarbons containing both aromatics and non-aromatics by extractive distillation with a solvent system containing dimethyl sulfoxide and optionally a co-solvent, preferably water, followed by distillation stripping of the aromatics from the enriched solvent system, and recycle of the lean solvent system to the extractive distillation step.