Inventors:
Wolfgang Kummer - Goslar, DE
Wilfried Gutknecht - Goslar, DE
James Gregory Olson - Arvada CO, US
Thomas R. Clark - Lakewood CO, US
International Classification:
C22B 3/18, C22B 3/06
Abstract:
The invention relates to a method of recovering molybdenum from a molybdenum bearing sulfide material. The material is contacted with a leaching solution in the presence of iron compounds and mesophilic or thermophilic iron oxidizing microorganisms and subsequently, a leaching process is performed by controlling the molar ratio of dissolved ferric iron to dissolved molybdenum. Preferably, a high amount and molar excess of dissolved iron is used. The presence of high concentrations of ferric iron in bioleach solutions allows iron-oxidizing microorganisms to grow and oxidize iron and bioleach molybdenite at dissolved Mo concentrations as high as 4. 4 g/L. Organic metabolites were not required for protecting cells from Mo toxicity. Maximum dissolution rates depend on reactor configuration, with agglomerated material simulating heap leaching of almost 1% Mo/day, but up to 10. 2% Mo/day in suspension/stirred reactor configurations, with rate highly dependent on temperature within the range of 25° C.