Inventors:
Gary A. O'Neill - Tyngsborough MA
George M. Goyak - Murrysville PA
Assignee:
Aluminum Company of America - Pittsburgh PA
International Classification:
C02F 128
Abstract:
A method for treating a pulp and paper manufacturing stream to remove colorants therefrom comprises: contacting the stream with a first adsorbent comprising the calcined product of a compound having the formula: A. sub. w B. sub. x (OH). sub. y C. sub. z. nH. sub. 2 O, wherein A represents a divalent metal cation; B a trivalent metal cation; C a mono- to tetravalent anion; and w, x, y, z and n satisfying the following: 0<z. ltoreq. x. ltoreq. 4. ltoreq. w. ltoreq. 1/2y and 12. gtoreq. n. gtoreq. 1/2(w-x); then contacting the stream with a second adsorbent consisting essentially of activated carbon. On a preferred basis, the first contacting adsorbent is a hydrotalcite derivative made by reacting activated magnesia with an aqueous solution of aluminate, carbonate, and hydroxyl anions before calcining at one or more temperatures between about 400. degree. -650. degree. C. There is further disclosed means for removing dioxins and adsorbable organic halogens, especially chlorinated phenols, from waste water solutions using the aforementioned combination of adsorbents.