Inventors:
Donald F. Othmer - Brooklyn NY
International Classification:
C22B 100, C22B 510, C22B 516
Abstract:
A reactor operating at a maximum temperature above 1535. degree. C and up to about 1950. degree. C is charged with a mixture of: (a) iron bearing titaniferous ore or its concentrate, or a residue from other operations containing iron and titanium, at least some of which is present as oxides, also (b) silica -- combined or separately added, also (c) one or more chlorides of a third metal of the alkaline or alkaline earth group, such as common salt and/or calcium chloride, also (d) a solid reductant as coke. Some impurities of the original material are removed as volatile chlorides or oxy-chlorides; the titanium also goes off as TiCl. sub. 4 in the gas stream, the iron is withdrawn as molten metallic iron, and the third metal added as the chloride: e. g. , the sodium of the common salt or the calcium of its chloride unites with the silica to give a silicate, such as sodium silicate (water glass) and/or calcium silicate which acts as a flux to remove the gangue from the iron. Most of the chlorine is supplied by the chlorine in this third-metal chloride through the separation by the chloride interaction with the iron and titanium: including that leaving in the titanium tetra-chloride, and in other volatile chlorides or oxy-chlorides, or remaining in the gangue as non-volatile chlorides.