Inventors:
Michael J. Hanner - Marietta OH, US
Clifford C. Pettey - Fleming OH, US
Carleton Stouffer - Bartlesville OK, US
Paul M. Hunt - Belpre OH, US
Ken E. Bowen - Belpre OH, US
Assignee:
Chevron Phillips Cheimcal Company, LP - The Woodlands TX
International Classification:
C08L 53/00, C08L 9/00, C08L 25/00, C08F 279/02, C08F 287/00
US Classification:
525 99, 525 88, 525 98, 525232, 525236, 525237, 525241, 525242, 525243
Abstract:
Compositions, processes, and methods are provided relating to styrenic polymers, including high impact polystyrene (HIPS), also referred to as rubber-modified polystyrene. In one aspect, a process is provided for making high impact polystyrenes, comprising the steps of combining a monovinylarene component, a monovinylarene-conjugated diene block copolymer, and a conjugated diene polymer. In another aspect, the feed components form an emulsion having a continuous phase and a dispersed phase. The continuous phase comprises at least a portion of the monovinylarene component and at least a portion of the conjugated diene polymer. The dispersed phase is suspended within the continuous phase, and comprises globules having at least a portion of the monovinylarene-conjugated diene block copolymer, a remaining portion of the monovinylarene component, and a remaining portion of the conjugated diene polymer. The monovinylarene component is polymerized in the presence of the emulsion alone or in the presence of other feedstocks.