CARL THOMAS PHILIPP
Engineers in Hot Springs, AR

5364447, Nov 15, 1994

Mar 29, 1993

8/038464

Carl T. Philipp - Hot Springs AR
Bobby H. Sims - Lonsdale AR

Enviroscience, Inc. - Hot Springs AR

C21B 1100

75500

A smelting process for blending hazardous and non-hazardous inorganic industrial wastes with carbon or aluminum reducing agents to simultaneously recover metal alloys (reducible metals), metal oxides (volatile reducible metals), carbon dioxide and man-made vitreous fiber (non reducible metals). Wastes including hazardous wastes of U. S. EPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or waste water to produce a homogeneous mass. The mass is formed into briquettes and melted in a cupola or plasma arc furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Calcium flux from calcium-stabilized wastes enhances mineral wool quality, lowers the sulfur content of metals and raises pH to facilitate metal reduction.

5496392, Mar 5, 1996

Mar 29, 1994

8/219527

Bobby H. Sims - Lonsdale AR
Carl T. Philipp - Hot Springs AR

Enviroscience - Hot Springs AR

C22B 700

75414

The present invention relates to a process for the production of metal alloys, metal oxides and slag-based products, such as mineral wool, from industrial waste materials. More specifically, the present invention relates to a process for recycling industrial waste materials into valuable commercial products, including, pure metals, metal alloys, metal oxides, and a molten slag comprising non-reducible metal oxides which thereafter can be converted to vitreous fiber and shot. Industrial waste materials suitable for use in the present invention include metal-containing waste products, particularly inorganic hazardous waste materials. The present process accomplishes total recycling in such a manner that the entire industrial waste material is consumed and converted to useful products.

5198190, Mar 30, 1993

Dec 21, 1990

7/632000

Carl T. Philipp - Hot Springs AR
Bobby H. Sims - Hot Springs AR

Enviroscience, Inc. - Little Rock AR

C22C 3304

420582

A method of recycling hazardous and non-hazardous industrial wastes to reclaim valuable metals, metal alloys, and metal oxides, and to produce mineral wool. Wastes including hazardous wastes of USEPA Series D, F, P, K, and U are pulverized and blended with liquids such as water or wastewater to produce a homogeneous mass. Calcium from calcium-stabilized wastes is used to enhance the quality of the mineral wool, lower the sulfur content, remove phosphorous, and raise pH to facilitate metal reduction. The mass is formed into briquettes and melted in a cupola or shaft furnace in the presence of carbon or aluminum to reduce metals. Other types of furnaces such as an electric arc furnace may be used to avoid the steps of forming and curing briquettes. Reduction is carried out at temperatures between 1660 and 3100 degrees Fahrenheit. Reducible metals are reduced and drawn off into molds.