Inventors:
Denis G. Fauteux - Acton MA
Arthur A. Massucco - Natick MA
John R. Powell - Burlington MA
Martin F. van Buren - Chelmsford MA
Assignee:
Arthur D. Little, Inc. - Cambridge MA
International Classification:
H01M 618, C08F 1800, C08G 200
Abstract:
Compounds are provided for use in an electrolyte comprising repeating unit selected from the group consisting of cyclic and heterocyclic species having y carbon atoms and z heteroatoms, X, and where y is 4, 5 or 6 and z is 0, 1 or 2. The heteroatom is selected from the group consisting of O, S and N. The repeating unit is further substituted by four to six pendant groups having the formula, (CHR. sub. 1). sub. m O(CHR. sub. 1 CHR. sub. 1 O). sub. n Y, where the majority of pendant groups comprises at least two O and further,
in which m is 0 or 1,
in which n is in the range of 0 to 25,
in which each R. sub. 1 is the same or different and R. sub. 1 is selected from the group consisting of H, alkyl, allylic and alkenyl radicals having 1 to 18 carbon atoms and Y, and
in which each Y is the same or different and Y is a functional group selected from the group consisting of polymerizable functionalities, plasticizing agents and ionic species. Electrolytes, plasticizers and macro-ions prepared from these compounds are described.